{"id":1217,"date":"2019-06-03T07:51:01","date_gmt":"2019-06-03T14:51:01","guid":{"rendered":"https:\/\/blogs.cdfa.ca.gov\/FREP\/?p=1217"},"modified":"2019-06-11T14:15:23","modified_gmt":"2019-06-11T21:15:23","slug":"examining-the-capabilities-of-biochar-to-adsorb-ammonium","status":"publish","type":"post","link":"https:\/\/blogs.cdfa.ca.gov\/FREP\/index.php\/examining-the-capabilities-of-biochar-to-adsorb-ammonium\/","title":{"rendered":"Research Update: Examining the Capabilities of Biochar to Adsorb Ammonium"},"content":{"rendered":"\n<p><strong>Project Title: <\/strong>Soil Biochar Amendment to Improve Nitrogen and Water Management<\/p>\n\n\n\n<p><strong>Project Leader: <\/strong>Suduan Gao, Research Soil Scientist, USDA-ARS<\/p>\n\n\n\n<p><strong>Project Location: <\/strong>San Joaquin Valley<\/p>\n\n\n\n<p><strong>Year of Study: <\/strong>Two of three<\/p>\n\n\n\n<p><strong>Overview: <\/strong>The goal of this study is to determine the overall benefits and best practices associated with the use of biochar, as a soil amendment, in vegetable crop production systems.<\/p>\n\n\n\n<p><strong>Issue: <\/strong>Nitrogen is an essential nutrient for crop growth, but without proper management, it can have direct environmental and human health impacts. Nitrate &nbsp;(NO<sub>3<\/sub><sup>&#8211;<\/sup>) that is not taken up by the crop can be leached from the root zone and contaminate groundwater. Additionally, ammonium (NH<sub>4<\/sub><sup>+<\/sup>), not used by the plant, can volatilize as ammonia and have a detrimental effect on air quality and human health (Figure 1). To reduce nitrogen loss to groundwater and the atmosphere and mitigate environmental impacts, Dr. Gao and her team are examining the capabilities of biochar to adsorb ammonium and nitrate.<\/p>\n\n\n\n<figure class=\"wp-block-image is-resized\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/i1.wp.com\/blogs.cdfa.ca.gov\/FREP\/wp-content\/uploads\/2019\/06\/volatilization-graphic.jpg?fit=648%2C501&amp;ssl=1\" alt=\"\" class=\"wp-image-1221\" width=\"591\" height=\"457\" srcset=\"https:\/\/blogs.cdfa.ca.gov\/FREP\/wp-content\/uploads\/2019\/06\/volatilization-graphic.jpg 1650w, https:\/\/blogs.cdfa.ca.gov\/FREP\/wp-content\/uploads\/2019\/06\/volatilization-graphic-150x116.jpg 150w, https:\/\/blogs.cdfa.ca.gov\/FREP\/wp-content\/uploads\/2019\/06\/volatilization-graphic-300x232.jpg 300w, https:\/\/blogs.cdfa.ca.gov\/FREP\/wp-content\/uploads\/2019\/06\/volatilization-graphic-768x593.jpg 768w, https:\/\/blogs.cdfa.ca.gov\/FREP\/wp-content\/uploads\/2019\/06\/volatilization-graphic-1024x791.jpg 1024w\" sizes=\"auto, (max-width: 591px) 100vw, 591px\" \/><\/figure>\n\n\n\n<p><em> Figure 1: Pathways that lead to N volatilization. Factors influencing these pathways include nitrogen source, soil pH, fertilizer placement and soil temperature. For more information on how these factors affect ammonia volatilization visit&nbsp; <\/em><a href=\"http:\/\/www.ipni.net\/publication\/nitrogen-en.nsf\/0\/B219184650778DB985257DD60005826A\/$FILE\/NitrogenNotes-EN-6.pdf\"><em>http:\/\/www.ipni.net\/publication\/nitrogen-en.nsf\/0\/B219184650778DB985257DD60005826A\/$FILE\/NitrogenNotes-EN-6.pdf<\/em><\/a><\/p>\n\n\n\n<p><strong>Methods: <\/strong>During 2018, the research team conducted a laboratory experiment to characterize seven biochars and determine their adsorption potential for NH<sub>4<\/sub><sup>+<\/sup> and NO<sub>3<\/sub><sup>&#8211;<\/sup>. A summary of the characterization study can be found in Table 1.<\/p>\n\n\n\n<figure class=\"wp-block-image\"><img loading=\"lazy\" decoding=\"async\" width=\"590\" height=\"290\" src=\"https:\/\/blogs.cdfa.ca.gov\/FREP\/wp-content\/uploads\/2019\/06\/biochar-characterization.png\" alt=\"\" class=\"wp-image-1218\" srcset=\"https:\/\/blogs.cdfa.ca.gov\/FREP\/wp-content\/uploads\/2019\/06\/biochar-characterization.png 590w, https:\/\/blogs.cdfa.ca.gov\/FREP\/wp-content\/uploads\/2019\/06\/biochar-characterization-150x74.png 150w, https:\/\/blogs.cdfa.ca.gov\/FREP\/wp-content\/uploads\/2019\/06\/biochar-characterization-300x147.png 300w\" sizes=\"auto, (max-width: 590px) 100vw, 590px\" \/><\/figure>\n\n\n\n<p><em>Table\n1. Selected properties of biochar produced from various feedstocks and\npyrolysis temperature<\/em><\/p>\n\n\n\n<p>To supplement the laboratory experiments, they are conducting field trials on onions and processing tomatoes to evaluate the effects of biochar incorporation on plant N uptake, ammonia volatilization and nitrate leaching. The field treatments include three irrigation levels with or without biochar amendments. The two biochars used were the almond shell char 550\u00b0C and softwood char 540\u00b0C.<\/p>\n\n\n\n<p><strong>Preliminary Results:<\/strong><\/p>\n\n\n\n<p>Both the adsorption of NH<sub>4<\/sub><sup>+<\/sup> and NO<sub>3<\/sub><sup>&#8211; <\/sup>were tested in the laboratory on the seven biochars. The characterization study showed a positive relationship between higher organic carbon density and NH<sub>4<\/sub><sup>+ <\/sup>adsorption. It also showed that higher pyrolysis temperatures and a pH above 9 may have a negative effect on adsorption capacity. The seven biochars are listed in Figure 2 with their relative ability to adsorb NH<sub>4<\/sub><sup>+<\/sup>.<\/p>\n\n\n\n<p>Of the seven biochars tested and characterized, none showed significant adsorption for NO<sub>3<\/sub><sup>&#8211;<\/sup>.<\/p>\n\n\n\n<figure class=\"wp-block-image\"><img loading=\"lazy\" decoding=\"async\" width=\"967\" height=\"249\" src=\"https:\/\/blogs.cdfa.ca.gov\/FREP\/wp-content\/uploads\/2019\/06\/Capture-biochar.png\" alt=\"\" class=\"wp-image-1219\" srcset=\"https:\/\/blogs.cdfa.ca.gov\/FREP\/wp-content\/uploads\/2019\/06\/Capture-biochar.png 967w, https:\/\/blogs.cdfa.ca.gov\/FREP\/wp-content\/uploads\/2019\/06\/Capture-biochar-150x39.png 150w, https:\/\/blogs.cdfa.ca.gov\/FREP\/wp-content\/uploads\/2019\/06\/Capture-biochar-300x77.png 300w, https:\/\/blogs.cdfa.ca.gov\/FREP\/wp-content\/uploads\/2019\/06\/Capture-biochar-768x198.png 768w\" sizes=\"auto, (max-width: 967px) 100vw, 967px\" \/><\/figure>\n\n\n\n<p><em>Figure 2: The relative adsorption of each biochar material with NH4+<\/em><\/p>\n\n\n\n<p>The\ndata from the first year of field trials on onions showed that there was no\nsignificant difference in plant growth or N uptake between the biochar and\nirrigation treatments. However, higher N leaching was observed in biochar\ntreatments, which supports the lab adsorption data mentioned above. The\npreliminary results from the tomato trial show similar trends where there were\nno significant differences among the treatments in ammonia volatilization and\nnitrate leaching. More results from the field trials will be available upon the\ncompletion of this project.<\/p>\n\n\n\n<p><strong>Impact: <\/strong><\/p>\n\n\n\n<p>While the laboratory experiment provided some evidence that biochar has the capacity to adsorb ammonium, data from the field trials suggests that the presence of biochar may not have a significant effect on N volatilization or leaching. However, biochar amendments may have the potential to improve soil health and productivity and help support a sustainable agricultural production system. The potential of biochar to increase soil organic carbon and improve soil physical properties should not be overlooked.<\/p>\n\n\n\n<p>For more information, the full project proposal can be found at: <a href=\"https:\/\/www.cdfa.ca.gov\/is\/docs\/16-0597-SA_Gao.pdf\">https:\/\/www.cdfa.ca.gov\/is\/docs\/16-0597-SA_Gao.pdf<\/a>.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Project Title: Soil Biochar Amendment to Improve Nitrogen and Water Management Project Leader: Suduan Gao, Research Soil Scientist, USDA-ARS Project Location: San Joaquin Valley Year of Study: Two of three Overview: The goal of this study is to determine the overall benefits and best practices associated with the use of biochar, as a soil amendment, in vegetable crop production systems. &hellip;<\/p>\n<div class=\"m-y-md text-right\"><a href=\"https:\/\/blogs.cdfa.ca.gov\/FREP\/index.php\/examining-the-capabilities-of-biochar-to-adsorb-ammonium\/\" class=\"btn btn-primary\" aria-label=\"Continue reading the blog post...\">Read More<\/a><\/div>\n","protected":false},"author":9,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_EventAllDay":false,"_EventTimezone":"","_EventStartDate":"","_EventEndDate":"","_EventStartDateUTC":"","_EventEndDateUTC":"","_EventShowMap":false,"_EventShowMapLink":false,"_EventURL":"","_EventCost":"","_EventCostDescription":"","_EventCurrencySymbol":"","_EventCurrencyCode":"","_EventCurrencyPosition":"","_EventDateTimeSeparator":"","_EventTimeRangeSeparator":"","_EventOrganizerID":[],"_EventVenueID":[],"_OrganizerEmail":"","_OrganizerPhone":"","_OrganizerWebsite":"","_VenueAddress":"","_VenueCity":"","_VenueCountry":"","_VenueProvince":"","_VenueState":"","_VenueZip":"","_VenuePhone":"","_VenueURL":"","_VenueStateProvince":"","_VenueLat":"","_VenueLng":"","_VenueShowMap":false,"_VenueShowMapLink":false,"footnotes":""},"categories":[86],"tags":[133,8],"class_list":["post-1217","post","type-post","status-publish","format-standard","hentry","category-all","tag-biochar","tag-california-fertilizer-research"],"post_mailing_queue_ids":[],"_links":{"self":[{"href":"https:\/\/blogs.cdfa.ca.gov\/FREP\/index.php\/wp-json\/wp\/v2\/posts\/1217","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/blogs.cdfa.ca.gov\/FREP\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/blogs.cdfa.ca.gov\/FREP\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/blogs.cdfa.ca.gov\/FREP\/index.php\/wp-json\/wp\/v2\/users\/9"}],"replies":[{"embeddable":true,"href":"https:\/\/blogs.cdfa.ca.gov\/FREP\/index.php\/wp-json\/wp\/v2\/comments?post=1217"}],"version-history":[{"count":4,"href":"https:\/\/blogs.cdfa.ca.gov\/FREP\/index.php\/wp-json\/wp\/v2\/posts\/1217\/revisions"}],"predecessor-version":[{"id":1235,"href":"https:\/\/blogs.cdfa.ca.gov\/FREP\/index.php\/wp-json\/wp\/v2\/posts\/1217\/revisions\/1235"}],"wp:attachment":[{"href":"https:\/\/blogs.cdfa.ca.gov\/FREP\/index.php\/wp-json\/wp\/v2\/media?parent=1217"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/blogs.cdfa.ca.gov\/FREP\/index.php\/wp-json\/wp\/v2\/categories?post=1217"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/blogs.cdfa.ca.gov\/FREP\/index.php\/wp-json\/wp\/v2\/tags?post=1217"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}